Heat from recombination or other events inside the cell cannot be distinguished from other chemical heat or nuclear heat.
However, it is very easy to determine that recombination is occurring, or that that it is not occurring. You do not measure the heat from it; you measure the electrolyte left in an open cell.
In a closed cells there is always recombination, and it never shows up as apparent excess heat. Shanahan's claim that heat sources shift in cells and cause spurious excess heat are wrong. That never happens.
Along similar lines, you can also measure the total amount of hydrogen absorbed in the cathode by measuring the "orphaned oxygen" left in the head space of a closed cell. There cannot be much, because the hydrogen to palladium ratio never reaches 1:1. Also because most cells are made of glass, and they would break if a lot of oxygen pressure built up. There is only a little orphaned oxygen, and therefore only a little absorbed hydrogen.
As I mentioned above, at the power levels observed in heat after death, if all of the hydrogen magically emerged from the cathode instantaneously, and if oxygen magically entered the cell, the power would be sustained for about 5 seconds before the fuel was used up. Since the cells remain hot for hours or days, that cannot explain the heat. As I said, this is impossible because there is no oxygen, only water vapor, and because it takes weeks for all of the hydrogen to come out.
The maximum apparent heat from recombination is easy to compute, and it is always far less than a cold fusion reaction. Thousands of times less, in some cases.
It is thousands of times less because only insignificant levels of recombination are observed. As I said, you can be 100% sure there is (or is not) recombination. In any open cell made by a professional electrochemist there will be none. The methods of avoiding it have been common knowledge since Faraday first described it.