That’s precisely why Biochar is a great tool, it couples with something we have to do (crop producing) and sequesters a fraction of that carbon in the cropping soils while enhancing their productivity.
Yes, charcoal resists decomposition, perhaps for hundreds or thousands of years. Not as long as solid coal buried deep underground, but for a long time. See:
"More important, unlike other organic fertilizers, charcoal is very stable and it will not decompose to carbon dioxide. So once applied, it will stay in soil for hundreds to thousands of years."
That is why you sometimes see the charred remains of a burned tree in a forest that has been there for a long time. It is also why people in Japan used to make the outside walls of houses and barns with charred wood. (I guess they still do, but you don't see it often.) I think I have seen this in New England as well. Much as I deplore Wikipedia . . . see:
Ash is no good for sequestration because the carbon is gone, as I said.