I have already mentioned several major concerns I have with the Wyttenbach's ResearchGate manuscript. Here is another, separate, concern. This one is less clear cut in my mind than the others because it is more along the line of a specialized issue in spectroscopy and I am not a spectroscopist.
Figure 1 of the manuscript shows 2 background-subtracted spectra. The idea of the background subtraction is to remove an additive signal that is present even in the absence of fuel - which is fine with me. But my issue here is it seems to me that the residual, background-subtracted, portion of the spectrum that is left should contain not only new peaks due to the fuel, but also a continuum signal due to scattering of the radiation coming from the fuel.
The implication of this is that even after background subtraction, each energy bin in the residual signal should have not just a contribution from any spectral line at that energy, but also many nonspecific contributions from all sorts of other lines at other energies. I think that the nonspecific component could be large compared to the actual line being sought for.
I don't see any consideration or compensation for this sort of thing in Wyttenbach's procedures. As far as I can see, lines are just recognized by seeing a certain bin having event counts sufficiently above background. But if much of that above-background signal is due to nonspecific contributions from gamma photons at other energy levels, then I think the quality of the procedure is called into question.
All this only occurred to me several days ago. It partly answers a question I posed in one of my first posts about Wyttenbach's data (here) --- 'Why is the shape of the background-subracted spectra so similar to that of the background itself?' I now realize that even after background subtraction, the spectrum is still very much shaped by the scattering of gamma radiation that is only present when the active fuel is present (and so cannot be background subtracted). This also makes sense of a comment from Paradigmnoia (here) who said that he used to subtract not just the background signal, but 2 to 3 times that background signal in order to isolate spectral lines of interest.