As to the "pure" alumina question..
I had previous posed an answer as a question in the hope that someone else would pick-up that XRD was not appropriate to determine the purity of a material. This is especially true where the XRD spectrum is not shown for independent analysis. I want to reiterate that (IMHO) XRD will provide a false impression if the diluent is amorphous (or of small crystalline size). This is often the case for binders.
From a quick search an interested party may wish to look at:
http://www.americanpharmaceuti…-Powder-X-ray-Diffraction
It refers to drugs and binders here the binders often outweigh the drugs but the principle will be the same for alumina. The broad background may be missed or ignored. Note the 10% comment.
XRF would have been a better methodology to apply and would have been much more meaningful for emissivity determinations as XRF only samples the near surface - say 20um (depends on the element and matrix).
Thus, everyone can be right - if the correct sample was taken, the XRD spectra could show 99.9% alumina. This does not mean 99.9% pure material. Reporting that XRD shows X does not mean that it is X. It just means that some analytical method say that it is and not supplying the actual data is a mistake.
The material may have been Durapot. But that can be 99.9% pure alumina plus lots of other amorphous binders and finely ground-up road dirt with lots of asphalt thrown in. You cannot tell. Reporting that it is 99.9% alumina would be correct.
The sample may not have been taken in the correct place. Who knows?
The sample may have been coated with some other paint. And guess what - it could be too thin to see by XRD or amorphous or not sampled.
Bottom line, they used the wrong analytical method. The analytical method reported X. And in end it really does not matter for this current case.
From my reading of Darden's EMAIL, the testers and Darden had a better handle on emissivity than tends to be made-out in this forum. Given the difficult testing situation with Dr. R, they did the best possible.
Dewey,
Wasn't there a shake-down of the 1MW plant in Italy? How good was that data set? Was it 250KW in and 250kW out? Or the dry vs. wet steam problem because no one sparged anything?