I think that working with hydrogen bottle is safer in some areas. But there are also next possibilities, that could end fatally.
If you are working with powder in correct environment, you can't do anything wrong. You can work with amount you wish and such amount is mostly very, very small.
In our experiments not more than 1g.
If you have hydrogen bottle, releasing 1g or 20grams might be without any noticement. Hydrogen can autoignite with air in some condictions, if you are overlooking some sealing issue, then your room or container may be full of hydrogen. This can't absolutely happen with powder. You can't exctract more hydrogen than what you have loaded.
LiAlH4 is not without hazards of its own. Besides the 4 moles of hydrogen that can be generated from one mole of LiAlH4 with water:
LiAlH4 + 4 H2O → LiOH + Al(OH)3 + 4 H2--- (molecular wt. of LiAlH4 is about 38, 4 H2 is about 8, so about 4.75 g of the solid hydride gives a gram of hydrogen. Put another way, one gram of LiAlH4 with water generates 0.21 g. of hydrogen, at 22.4 mol / liter, that says it can release about 2.2 liters of hydrogen gas.
Either the hydride or hydrogen in small quantities can still give a nasty surprise, if rapid oxidation of hydrogen with air drives glass or metal into vital tissues such as the eyes.
But, we still have not defined the lack, or presence, of an aneutronic production of beryllium from this system. Beryllium 8 from addition of a proton to the natural 92% lithium 7 immediately decays to two alphas of low penetration energy (at 103 keV, generally harmless unless the decay occurred inside living cells).
HOWEVER, if Be is produced from say the 7+% lithium 6 natural component and yields 7Be it is an entirely different story. Be 7 has all the extreme physiological toxicity of beryllium itself, as I mentioned here some months back, but further, unlike the beryllium 8 with prompt decay to helium, the beryllium 7 isotope is radioactive, having a 54.5 day half life releasing a 479 keV gamma. Freethinker's recent CPM reports remind us we do not yet understand everything concerning this LENR system.