>>Hank, So many questions!...
Chemists know that if you want interesting reactions to occur with nickel then the oxide needs to be reduced to pure nickel metal. Pure nickel metal absorbs hydrogen on to (or into?) its surface, creating highly reactive sites that can catalyze a variety of chemical reactions. Rossi says he's using nickel. I am assuming he means nickel metal.
Deoxidizing (i.e. reducing) nickel oxide is a pretty routine chemical process. However, it's best done under positive H2 pressure (15-25 Bar) and by starting at low temperature (~180C) and raising that temperature up by about 20C per hour until you reach ~380C and then soak there for a further 8 hours (approx). With flushing of course to remove the H2O produced (& condensed and measured) and provision of more pure Hydrogen as required. Electrolytic grade hydrogen required (with zero ppm CO+CO2) or else the active nickel sites will be contaminated with carbonyl ligands.
OTOH, what little knowledge I have concerning Lithium and LiAlH4 is all derived from a variety of Wikipedia articles and the references. Very interesting.
My first-hand experience was of very rapid temperature runaways (to >>1,000 degrees C) leading to damaged thermo-couples and clumps of fused nickel metal. Nickel melts at 1445C. These temperature "excursions" (once or twice a week) in the laboratory I was supervising in 1972/73 were a damn nuisance!
The temperature required for LENR to happen seems to vary enormously depending upon the experimental set-up circumstances! My own particular experience with nickel and hydrogen inclines me towards believing a Rossi-type reactor (as per the photograph included in Mat Lewan's book) will actually work.
The nuclear reaction of high-energy protons with lithium is well known to science (since 1932). It produces high-energy alpha particles. What seems to be NOT so well known to science is what happens to Hydrogen inside Nickel. How does nickel "catalyze" conversion of hydrogen atoms into high-energy protons?