The paper of Holmlid and his polish colleagues "Production of ultra-dense hydrogen H(0): A novel nuclear fuel" been discussed a few times in this thread.
The proposed fundamental mechanism is illustrated in Fig. 3 with the assumption that hydrogen that is transported over the (heated) surface of the solid (in this case the Alkali doped iron oxide) in a gaseous environment.
Dissociated hydrogen atoms and alkali Rydberg matter clusters exchange energy such that hydrogen Rydberg matter is formed which in turn condensates to UDH. The low working function of alkali metals plays an essential role in this mechanism.
There are many indications that just high enough absorption of hydrogen or deuterium in suitable metals (e.g. Pd, Ni) can lead to excess heat.
The question is whether this is also related to the formation of UDH, as Holmlid has shared as a remark at ResearchGate.
Let's assume this is the case. The question then is how can UDH be formed within such metals.
One thought could be that the work function of absorbed hydrogen atoms within the lattice of such metals is much lower than that of dissociated hydrogen in gaseous form above solid surfaces. Hydrogen atoms with a comparable or lower work function would than form hydrogen Rydberg matter in a similar manner as alkali metals.
Another thought could be that the work function of metals that have a very high load of hydrogen within their lattices is significantly lower than that of metals that don't contain hydrogen.
Or, it might be a combination of the two thoughts of course.
The open question therefore is: would it be possible that the work function of hydrogen and/or metals atoms is decreased within the lattices of such metals when sufficient hydrogen atoms are present?
I was not been able to find any scientific publications on this unfortunately. Any thoughts or facts?