The y-axis is the log of 100 times "enthalpy generation / joule enthalpy input." That does not seem to correlate with anything in Table 1. And why is it "Joule" enthalpy input and not "Watt"? At peak, it is 100 * 3 = 300 times . . . what?And what does "enthalpy generation" mean, anyway? Is that excess heat? (~10 W just after 1.6 million seconds.) Or is it input power plus excess heat? (~17 W just after 1.6 million seconds, I think.) Why is it multiplied by 100?? I am confused!
it is pretty confusing.
(1) it must be the ratio of excess heat / heat in (or just possibly total heat out / heat in) averaged over some small period - because if it was total heat out / in you could not get a graph of that shape with sharp changes. So basically it is excess power out / power in or possibly total power out / power in.
(2) the 100 X is weird but as above makes sense if it is a percentage.
(3) the log is very weird - but the values in the graph do make sense of this.
Thus log10 (%age excess pout / pin) would be:
pout = pin => 0 % => - infinity (we do not see this)
log (%age total power out ./ power in):
pout = pin => 100% => 2 (after the log). Most of the graph is a bit below that.
pout = 10*pin => 1000% => 3 (after the log). Seems reasonable for a large heat burst as is claimed.
Using this interpretation that system is mostly endothermic, absorbing heat, especially at the start (which makes sense). However there is a large power generation burst of up to (instantaneously) about 10X the input.
I realise a few of the things about this interpretation are guessed. But the alternatives are I think all eliminated as not being compatible with the given graph.
So: y = log10(100*Pout/Pin)
Pout - instantaneous power out (total = Pin + Pexcess)
Pin - instantaneous power in (from heater hence joule enthalpy).
The other possible fit would be to suppose that both the 100X and the log annotation on the Y axis are mistakes. In which case this could reasonably just be Pout / Pin - with the reaction clearly exothermic over some time, but the heat burst much less significant.